$re = '/[22-99]{2}[A-Z]{2}[0-9]{4}[A-Z]{2}[0-9A-Z]{1}[0-9]{5}[A-Z]{1}[0-9]{1}/m';
$str = '22DE4701AEM15487R1
22DE4701BB025132C5
23DE3302CEA45678R6
23DE7650EEH54214R9
23DE6150APH12542R3
23DE6150KFA21587R7
22DE6150JHM36859R8
23DE4701DCA12345R4
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php