$re = '/@require (.+?)?(?:-->|\s)/m';
$str = '<head>
<meta charset="UTF-8">
<title></title>
<!--@require a.css-->
<!--@require BOWER/jquery-->
<!--@require /build/bundle-->
<!--
@require bootstrap
@require bootstrap.css
@require bootstrap.font
-->
</head>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php