$re = '/(?=(?:[A-Za-z\.#\*]))((?<=(?:[\s])|(?<=^)))[a-z-\[\]:{1,2}#\.\*]+(\s+)?{/m';
$str = 'custom {
}
custom {
}
custom-tag.lol {
}
custom-tag[lol] {
}
custom-tag:active {
}
custom-tag::after {
}
.lol {
custom-tag {
}
}
[a-z-\\[\\]:{1,2}#\\.\\*]+(\\s+)?{
(?(?=\\w) (?<!\\w) | (?<!\\W) )
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php