$re = '/.*?([A-Z][a-z]*)\s+([A-Z][a-z]*)\s+(([A-Z])([A-Z])[0-9]{5}\5\4)\s+(\S+@\S+).*/';
$str = 'Name list from PQP-97 system &%$ Bill Williams MK12345KM bwilliams01@msn.com ^ %20%
Bill Williams MK12345KM bwilliams01@msn.com
Fredericka Hanover GW22887WG freddie@verizon.net
Fredericka Hanover GW22887WG freddie@verizon.net';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php