$re = '/<[^C]*CATEG="([^"]+)"[^>]*>([^<]+)/';
$str = 'História do RFID A tecnologia de <EM ID="hub-30518" CATEG="PESSOA">RFID </EM>tem suas raÃzes nos sistemas de radares';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php