$re = '/,(?<!("|\/|\\\\))(\b\d+\b)(?!("|\/|\\\\|( \d)))/';
$str = '"87",0000,0767,"078",0785,"0723",23487, "061 904 5284","17\\/10\\/2016","some.name.789@hotmail.com"';
$subst = ",\"$2\"";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php