$re = '/TimesAccessed[[:punct:]]+(?<TimesAccessed>[^\",]+)/m';
$str = 'Message: PublicDomainAPI.SaveAsync: progresses = [{"UserGuid":"0a062514-def3-4ae5-9092-asd12easd","CourseId":"c71f6538-e379-447e-aaf3-asd1dasd","Status":"InProgress","UserScore":1,"TotalTime":"0:23:45","TimesAccessed":null,"CompletionDate":null,"LastTimeAccessed":"2022-07-23T09:59:12.191+00:00","SuccessStatus":"Pass","Bookmark":"en","SuspendData":null,"Progress":null,"RegistrationDate":"2022-07-23T09:59:12.191+00:00","RegistrationNumber":1}], total: 1';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php