$re = '/\((\d+),0,\'(([^\']|\\\\\')+)\',0/';
$str = '(500,0,\'ABC\',4),(550,0,\'ABC\',0),(450,0,\'D\\\'E,F\',0),(650,0,\'G_HI\',0);';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php