$re = '/^(\d{4}[A-Z]{2}) ([\w\.\'\/\- ]+) (\w?[0-9]+[a-zA-Z0-9\- ]*)/im';
$str = '# Simple
5913ST PRINSENSTRAAT 6
3421ED OUDE SINGEL 11-21
6546EX HORSTACKER 16-44 A
5473CA PLEIN 1969 13A
6533VD ST. JACOBSLAAN 339
7622CN \'T DIJKHUIS 36
5022EH PATER V/D ELSENPLEIN 86
6533VD P/A ST. JACOBSLAAN 339
3262JP WEST-VOORSTRAAT 20
6212BP GLACISWEG 30 K-L
6216BX BECANUSSTRAAT 15A04
9663PR ALBATROSSTRAAT B75
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php