$re = '/(([0-9]){2}:){3}([0-9]){2}/';
$str = '@ This file written with the Avid Caption plugin, version 1
<begin subtitles>
00:00:08:00 00:00:14:03
070
00:00:14:03 00:01:02:19
085
00:01:02:19 00:01:37:04
075
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php