$re = '/"([^"]*)".*/';
$str = '2014-03-20 16:53:39.741 -0700 Information 638 NICOLE Client "[WebDirect]" opening a connection from "24.114.54.155 (24.114.54.155)" using "iPad Safari 7.0 [fmwebdirect]".
2014-03-20 16:53:39.741 -0700 Information 94 NICOLE Client "[WebDirect] (24.114.54.155) [24.114.54.155]" opening database "ProShopPartner_v1" as "[Guest]".
2014-03-20 16:58:45.163 -0700 Information 98 NICOLE Client "[WebDirect] (24.114.54.155) [24.114.54.155]" closing database "ProShopPartner_v1" as "[Guest]".
2014-03-20 16:58:45.163 -0700 Information 22 NICOLE Client "[WebDirect] (24.114.54.155) [24.114.54.155]" closing a connection.';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php