$re = '/(?:^|[\W])(@\w{1,20})(?:$|[\W])/m';
$str = '@ih knkl @gs fsdf@ijkjdsfkl "@_dsfkoj" @sdkj-s @ℍ𝕦𝕘𝕠𝕄𝕠𝕤𝕙 s @ljbhdkj_sa3 wefd s|jhh "@nksdm" hugo@mis.com @dsf
@𝕘𝕠𝕄𝕠𝕤𝕙 dfs @! @fdsdfasdfsdfsdfsdfsdfs @last @k @jj. @sdf.sd ';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php