$re = '/(\d{2}h\d{0,2})/';
$str = '"programacao": "11h Abertura – Som Mecânico 12h30 Lino e Orquestra 15h30 Volkstanzgruppe Blauer Berg - Timbó - SC (Infanto Juvenil) 15h45';
$subst = "<br>\1";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php