$re = '/structure\s+([\w.-]+)\s*((?:(?!end\s+\1)[\s\S])*)end\s+\1/m';
$str = 'structure NAME_PART_1
Some content
block NAME_PART_2
Some other content
end NAME_PART_2
block NAME_PART_3
subblock NAME_PART_4
Some content++
end NAME_PART_4
end NAME_PART_3
end NAME_PART_1
structure
NAME_PART_5
end NAME_PART_5';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php