$re = '/^-?(((([0][0-9])|([1][0-3])):(([03][0])|([14][5])))|14:00)/m';
$str = '00:00
01:00
00:15
00:30
00:45
01:30
04:00
05:00
06:30
10:00
13:00
14:00
13:30
14:30
20:00
24:00
-14:00
-13:30
-10:00
-09:00
-00:00
00:10
00:20
00:25:
00:35';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php