$re = '/(\{(?:[^{}]++|(?1))*})(*SKIP)(*F)|\|/m';
$str = 'help {Jason|Maria|Santa|{Lucia|Raul}\'s father}|go to school
help {Jason|Maria|Santa|{Lucia|Raul}\'s father}
go to school
Jason|Maria|Santa|{Lucia|Raul}\'s father
Jason
Maria
Santa
{Lucia|Raul}\'s father';
$subst = "\n";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php