$re = '/([^"]|^)(Level\s+\d+)([^"]|$)/m';
$str = 'Level 2 He is Level 2 but not Level 2 ss "Level 5 but he may be "Level 2" but Level 8" too Level 2';
$subst = "\1\"\2\"\3";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php