$re = '/\bPassword\sarchivio:\s\d+\n\n\nPer\sconto\sdi:\s/m';
$str = '
Password archivio: 6646
Per conto di: pec@pec.anekitalia.com
posta-certificata@telecompost.it';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php