$re = '/<(PUB_DATE|DATE_COLLECT_100)>([[:digit:]]{4}-[[:digit:]]{2}-[[:digit:]]{2}T[[:digit:]]{2}:[[:digit:]]{2}:[[:digit:]]{2})Z<\/\1>/m';
$str = '<PUB_DATE>2021-06-25T21:17:51Z</PUB_DATE>
<DATE_COLLECT_100>2021-06-25T21:17:51Z</DATE_COLLECT_100>';
$subst = "<$1>$2.001Z</$1>";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php