$re = '/^(?=.*\bKeyWord2\b)|\G.*?\K\bKEYWORD1\b/m';
$str = 'The KeyWord2 before one KEYWORD1 here
The KEYWORD1 before one KeyWord2 here
The KEYWORD1 before KeyWord2 then KEYWORD1 and KEYWORD1 again
The KeyWord2 before KEYWORD1 and KEYWORD1 again
The KEYWORD1 before one KeyWord99 here
The KEYWRD before one KeyWord2 here
';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php