$re = '/<td.*?class="wertCaption".*?>(?<value>[^<]*)/m';
$str = '<td class="balkenL"><div style="width:16px;background-color:#D30029;"> </div></td>
<td class="wertL"><span>107,35</span></td>
<td class="wertCaption">Fehlpässe</td>
<td class="wertR">104,82</td>
<td class="balkenR"><div style="width:16px;background-color:#C2BFBF;"> </div></td> ';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php