$re = '/(?!\w.*>)(&)(?=.*<\/)/';
$str = 'Walter & Cooper';
$subst = "result context-3=\"131180\" context-ui-effect=\"key-change\" control-mode=\"bns\" /";
$result = preg_replace($re, $subst, $str, 1);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php