$re = '/(?P<response_time>\s\d+\.\d+\s)/';
$str = '192.168.1.1 - - [08/Sep/2014:15:15:15 +0100] "GET / HTTP/1.0" 200 612 "-" "-" 4.038 ';
preg_match($re, $str, $matches, PREG_OFFSET_CAPTURE, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php