$re = '/RTL_433toMQTT\/([^\/:]+)\/?:.* /m';
$str = 'rtl433:home/rtl433/RTL_433toMQTT/Rubicson-Temperature/1/244:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Nexus-TH/1/9:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/WT450-TH/1/1:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Secplus-v1/0:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Interlogix-Security/motion/485865:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Generic-Motion:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/LaCrosse-TX141THBv2/0/168:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Acurite-609TXC/0:.* { json2nameValue($EVENT) }
rtl433:home/rtl433/RTL_433toMQTT/Acurite-609TXC/128:.* { json2nameValue($EVENT) }';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php