$re = '/^(?:Copy of )?(?P<showName>.*?)(?: - )?(?P<episode>S\d\dE\d\d)$/m';
$str = 'Bleach S01E02
Attack on Titan S03E03
Bleach - S11E12
Attack on Titan - S19E20
Copy of Attack on Titan - S10E10
Copy of Bleach - S01E02';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php