$re = '/<TransactionID>(?<transID>.*?)<\/TransactionID>.*?<ActionCode>(?<actcode>.*?)<\/ActionCode>.*?<Token>(?<token>.*?)<\/Token>.*?<Approval>(?<approv>.*?)<\/Approval>.*?<CVV2>(?<cvv>.*?)<\/CVV2>.*?<ResponseText>(?<respon>.*?)<\/ResponseText>.*?<VerificationResult>(?<verify>.*?)<\/VerificationResult>|<TransactionID>(?<transID2>.*?)<\/TransactionID>.*?<ActionCode>(?<actcode2>.*?)<\/ActionCode>.*?<ResponseText>(?<respon2>.*?)<\/ResponseText>/m';
$str = '<ippayResponse><TransactionID>K20201022144133757</TransactionID><ActionCode>000</ActionCode><Token>4E3C5K3B7H0A1000</Token><Approval>TEST35</Approval><CVV2>N</CVV2><ResponseText>APPROVED</ResponseText><VerificationResult>0</VerificationResult></ippayResponse>';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php