$re = '/(?i)(?:\G(?!\A)|Catch(?:This|That|Anything)\s*\()[^()"]*\K"/';
$str = 'Any text and "much" "more" of it. Don\'t replace quotes here
CatchThis( no quotes here, "any more text" , "and so on and so forth...")
catchthat("some other text" , "or less")
some text in "between"
CatchAnything ( "even more" , "and more", no quotes there, "wall of text")
more ("text"""") and quotes after...';
$subst = "#";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php