$re = '/^[A-Z]?\d+(?:\.\d+)?(?:\s{1,10}|\\\\n)(?:[A-Z][a-z]+ ?)+/m';
$str = '3.1 Introduction
3 Battery
3.1\\nIntroduction
A1 Introduction
A1.1 String
B3 Battery Tests
I3.1 Etc';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php