$re = '/(<img.*?src=")((?:\w+\/)+?)([\w-]+\.(?:jpg|jpeg|png|gif))"/';
$str = '<img src="index_files/bottle2.jpg" name="product ds Grodsdwth" class="pullleft">
<img title="" src="index_files/ss-button.png" class="step-btn" alt=""></a>
<img src="index_files/a/bottle2.jpg" name="product ds Grodsdwth" class="pullleft">';
$subst = "$1{#CDNPath#}img/$3\"";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php