$re = '/\\\\"SocRole\\\\":\s\\\\"([^\\\\]+)|\\\\"PermissionGroup\\\\":\s\\\\"([^\\\\]+)/m';
$str = '\\"Email\\": \\"testesiem@gmail.com\\",
\\"Environments\\": [
\\"*\\"
],
\\"LicenseType\\": \\"Regular\\",
\\"PermissionGroup\\": \\"Admins\\",
\\"SocRole\\": \\"Administrator\\",
\\"UserType\\": \\"External\\"
}"
\\"Email\\": \\"AymanC@gmail.com\\",
\\"Environments\\": [
\\"*\\"
],
\\"LicenseType\\": \\"Regular\\",
\\"PermissionGroup\\": \\"Admins\\",
\\"SocRole\\": \\"Administrator\\",
\\"UserType\\": \\"External\\"
}"
\\"Email\\": \\"Aym4nn@gmail.com\\",
\\"Environments\\": [
\\"*\\"
],
\\"LicenseType\\": \\"Regular\\",
\\"PermissionGroup\\": \\"Admins\\",
\\"SocRole\\": \\"Administrator\\",
\\"UserType\\": \\"External\\"
}"';
preg_match_all($re, $str, $matches, PREG_SET_ORDER, 0);
// Print the entire match result
var_dump($matches);
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php