$re = '/^(.*?)\s*#quote {(.*?)\s*}(.*)(#quote {)(.*?)(}.*)$/s';
$str = '#any1 {
}
#quote {
padding-bottom: 20px;
font-size: 3.6vmin;
}
#any2 {
}
#quote {
text-align: center;
}
#any3 {
}';
$subst = "\1\3\4\2\5\6";
$result = preg_replace($re, $subst, $str, 1);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php