$re = '/^(?:\"(.+?)\"|([^\s]+)).*/m';
$str = 'c:\\tools\\foo.exe
c:\\tools\\foo.exe -bar
"C:\\Program Files\\bar.exe"
"C:\\Program Files\\bar.exe" -baz
';
$subst = "$1$2";
$result = preg_replace($re, $subst, $str);
echo "The result of the substitution is ".$result;
Please keep in mind that these code samples are automatically generated and are not guaranteed to work. If you find any syntax errors, feel free to submit a bug report. For a full regex reference for PHP, please visit: http://php.net/manual/en/ref.pcre.php